allylic


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Related to allylic: Allylic substitution
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Words related to allylic

of or pertaining to the allyl radical

References in periodicals archive ?
1999) found that the monoterpenes may undergo oxidative reactions that result in aromatic compounds, cleavage of C-C double bonds, epoxide formation, or allylic oxidation to alcohols, ketones, and aldehydes.
The extent of oxidative rancidity was measured using the iodine value (IV), peroxide value (PV), oxidative stability index (OSI), thiobarbituric acid (TBA) and free fatty acids (FFA), anisidine value (AV), allylic position equivalents (APE), bis-allylic position equivalents (BAPE), and microbial plate count on standard plate count agar.
These products are prepared in a proprietary process using hydroxy-functional allylic monomers.
The most famous asymmetric oxidation catalyst is Sharpless-Katsuki complex, which is known as a tool for asymmetric epoxidation of allylic alcohols [8, 9].
158 BROWN JM,TETRAHEDRON,vol 0050,page 4493,1994,cites= 30,MECHANISTIC AND SYNTHETIC STUDIES IN CATALYTIC ALLYLIC ALKYLATION WITH PALLADIUM COMPLEXES OF 1-% 2-DIPHENYLPHOSPHINO -1- NAPHTHYL [is less than] ISOQUINOLINE
21) proposed that EVA underwent degradation to generate allylic radicals (scheme 1).
This approach includes the use of allylic functionality in the latex, alkyd-acrylic latexes, latexes incorporating soya oil in the polymer backbone or side chain, and the use of small amounts of diene monomers (e.
If MIC values for royleanones 8 (with a C-13 allylic side chain) and 9 (with a C-13 acetoxyisopropyl side chain) are compared with the MIC values of the analogous horminone (3), it is clear that the C-13 isopropyl side chain of 3 confers higher activity against the clinical strains assayed, as already referred for Gram-positive antibacterial activity (Yang et al.
This volume of the series contains two chapters, on the allylic trihaloacetimidate rearrangement, and the asymmetric dihydroxylation of alkenes.
During her graduate studies, she worked at the development of new methodologies for the stereoselective cyclopropanation of allylic alcohols and she performed the total enantioselective synthesis of a natural polycyclopropane, (+)-U-106305.
The C-11 allylic methyl group may be oxidized to 11-hydroxy-tetrahydrocannabinol (11-OHTHC), a pharmacologically active metabolite.
Palladium-complexes form effective catalysts for allylic alkylations and Silver (I)-complexes form efficient catalysts for asymmetric [3 + 2] cyclization reactions.
Sartomer's new CN 9101 aliphatic oligomer is a 100% reactive, allylic functional aliphatic oligomer that can be used in low temperature or photo-cured free radical polymerizations as a latent initiator or crosslinker.