benzylic


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Related to benzylic: allylic
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Words related to benzylic

relating to benzyl

References in periodicals archive ?
The mechanism of action is likely to be similar to that of MSD, in that radical trapping by C=C addition yields a resonance-stabilized benzylic radical (Scheme 7) [31].
Silane (13) has a chlorine atom bonded to an allylic group, and silane (4) has a chloride bonded to a benzylic group.
ACENTRIC ACHROMIC BELONGED BENZYLIC BIOPSIED CENTROID CHORUSED COSTUMED DEFORMED DELOUSED DIOPTRIC EMPURPLE FORTUNED FORTY-ONE GLORY-PEA HIRSUTED INSTROKE INTURNED LOST LIFE (BI) MORWYNGE
of significant positive charge at the benzylic position in the
9 ppm with two hydrogen in integration, it was unclear for us to assign it whether the alpha hydrogen on 16th carbon or the benzylic hydrogen on 10th carbon.
Pincock has begun to obtain a real understanding of the factors that control the competition between homolytic and heterolytic photocleavage of benzylic substrates and is trying to apply these principles to develop synthetically useful procedures.
Due to the benzylic chlorine, a great number of nucleophilic substitutions are made possible, leaving the double bond undamaged and providing new monomers that can be polymerized or copolymerized when the experimental conditions are well chosen (16), (17).
BIMSM can be cured efficiently via the benzylic bromine sites and requires only low levels of curatives for effective vulcanization.
This volume of the series consists of two chapters, on catalytic enantioselective aldol addition reactions, and benzylic activation and stereochemical control in reactions of tricarbonyl(arene)chromium complexes.
20 (8H) can be assigned to the protons of the benzoate group plus the benzylic protons ortho to the--C[H.
benzylic = allylic > tertiary carbon > secondary carbon > primary carbon > vinylic >> phenyl
Bromi-nated poly(isobutylene-co-paramethyl styrene) (BIMS, EXXPRO 3745, benzylic bromide content = 0.
With only a few benzylic bromine groups along a given BIMS chain that are interacting with CB particles, it was proposed that either a single BIMS chain is absorbed onto several filler aggregates or long loops are formed for absorbed chains.
In the same way, hydrogens on benzylic and allylic carbons are more easily abstracted than hydrogens found in polymers.